Abstract: The change of the shell structure in atomic nuclei, so-called “nuclear shell evolution”, occurs due to changes of major configurations through particle-hole excitations inside one nucleus, as well as due to variation of the number of constituent protons or neutrons. We have investigated how the shell evolution affects Gamow-Teller (GT) transitions that dominate the beta decay in the region below Sn-132 using the newly obtained experimental data on a long-lived isomer in Ag-127. The T-1/2 = 67.5(9) ms isomer has been identified with a spin and parity of (27/2(+)) at an excitation energy of 1942(-20)(+14) keV, and found to decay via an internal transition of an E3 character, which competes with the dominant beta-decay branches towards the high-spin states in Cd-127. The underlying mechanism of a strong GT transition from the Ag-127 isomer is discussed in terms of configuration-dependent optimization of the effective single-particle energies in the framework of a shell-model approach.