Abstract: Challenging neutron-capture cross-section measurements of small cross sections and samples with a very limited number of atoms require high-flux time-of-flight facilities. In turn, such facilities need innovative detection setups that are fast, have low sensitivity to neutrons, can quickly recover from the so-called. gamma-flash, and offer the highest possible detection sensitivity. In this paper, we present several steps towards such advanced systems. Specifically, we describe the performance of a high-sensitivity experimental setupat CERN n_TOF EAR2. It consists of nine sTED detector modules in a compact cylindrical configuration, two conventional used large-volume C6D6 detectors, and one LaCl3(Ce) detector. The performance of these detection systems is compared using Nb-93(n, gamma) data. We also developed a detailed GEANT4 Monte Carlo model of the experimental EAR2 setup, which allows for a better understanding of the detector features, including their efficiency determination. This Monte Carlo model has been used for further optimization, thus leading to a new conceptual design of a gamma detector array, STAR, based on a deuterated-stilbene crystal array. Finally, the suitability of deuterated-stilbene crystals for the future STAR array is investigated experimentally utilizing a small stilbene-d12 prototype. The results suggest a similar or superior performance of STAR with respect to other setups based on liquid-scintillators, and allow for additional features such as neutron-gamma discrimination and a higher level of customization capability.