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Pi, M., Barranco, M., Navarro, J., & Ancilotto, F. (2012). Nucleation and cavitation in parahydrogen. Chem. Phys., 399, 213–217.
Abstract: We have used a density functional approach to investigate thermal homogeneous nucleation and cavitation in parahydrogen. The effect of electrons as seeds of heterogeneous cavitation in liquid parahydrogen is also discussed within the capillary model.
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Borja, E. F., Garay, I., & Strobel, E. (2012). Revisiting the quantum scalar field in spherically symmetric quantum gravity. Class. Quantum Gravity, 29(14), 145012–19pp.
Abstract: We extend previous results in spherically symmetric gravitational systems coupled with a massless scalar field within the loop quantum gravity framework. As a starting point, we take the Schwarzschild spacetime. The results presented here rely on the uniform discretization method. We are able to minimize the associated discrete master constraint using a variational method. The trial state for the vacuum consists of a direct product of a Fock vacuum for the matter part and a Gaussian centered around the classical Schwarzschild solution. This paper follows the line of research presented by Gambini et al (2009 Class. Quantum Grav. 26 215011 (arXiv: 0906.1774v1)) and a comparison between their result and the one given in this work is made.
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Hernandez, P. (2012). CP violation in the neutrino sector: The new frontier. C. R. Phys., 13(2), 186–192.
Abstract: The discovery of neutrino masses has revealed a new flavour sector in the Standard Model. Just like the quark flavour sector, it contains a seed of CP violation, resulting in an asymmetric behaviour of matter and antimatter. It is argued that this new source of leptonic CP violation may be discovered in more precise neutrino oscillation experiments involving neutrino beams with energies in the GeV range that will be sent to distances of a few thousand kilometres.
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David, M., Borges, G., Gomes, J., Pina, J., Campos, I., Fernandez, E., et al. (2012). Software Provision Process For EGI. Comput. Inform., 31(1), 135–148.
Abstract: The European Grid Initiative (EGI) provides a sustainable pan-European Grid computing infrastructure for e-Science based on a network of regional and national Grids. The middleware driving this production infrastructure is constantly adapted to the changing needs of the EGI Community by deploying new features and phasing out other features and components that are no longer needed. Unlike previous e-Infrastructure projects, EGI does not develop its own middleware solution, but instead sources the required components from Technology Providers and integrates them in the Unified Middleware Distribution (UMD). In order to guarantee a high quality and reliable operation of the infrastructure, all UMD software must undergo a release process that covers the definition of the functional, performance and quality requirements, the verification of those requirements and testing in production environments.
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Dul, M. C., Lescouezec, R., Chamoreau, L. M., Journaux, Y., Carrasco, R., Castellano, M., et al. (2012). Self-assembly, metal binding ability, and magnetic properties of dinickel(II) and dicobalt(II) triple mesocates. CrystEngComm, 14(17), 5639–5648.
Abstract: Two metallacyclic complexes of general formula Na-8[(M2L3)-L-II]center dot xH(2)O [M = Ni (4) and Co (5) with x = 15 (4) and 17 (5)] have been self-assembled in aqueous solution from N,N'-1,3-phenylenebis(oxamic acid) (H4L) and M2+ ions in a ligand/metal molar ratio of 3 : 2 in the presence of NaOH acting as base. X-Ray structural analyses of 4 and 5 show triple-stranded, dinuclear anions of the meso-helicate-type (so-called mesocates) with C-3h molecular symmetry. The two octahedral metal-tris(oxamate) moieties of opposite chiralities (Delta, Lambda form) are connected by three m-phenylene spacers at intermetallic distances of 6.822(2) (4) and 6.868(2) angstrom (5) to give a metallacryptand core. In the crystal lattice, the binding of these heterochiral dinickel(II) and dicobalt(II) triple mesocates to sodium(I) ions leads to oxamato-bridged heterobimetallic three-dimensional open-frameworks with a hexagonal diamond architecture having small pores of 17.566(4) (4) and 17.640(2) angstrom (5) in diameter where the crystallization water molecules and the sodium(I) countercations are hosted. Variable temperature (2.0-300 K) magnetic susceptibility measurements reveal relatively anisotropic S = 2 Ni-2(II) (4) and S = 3 Co-2(II) (5) ground states resulting from the moderate to weak intramolecular ferromagnetic coupling between the two high-spin Ni-II (S-Ni = 1) or Co-II (S-Co = 3/2) ions across the m-phenylenediamidate bridges [J = +3.6 (4) and +1.1 cm(-1) (5); H = -JS(1)center dot S-2]. A simple molecular orbital analysis of the electron exchange interaction identifies the p-type pathways of the meta-substituted phenylene spacers involving the d(z2) and d(x2-y2) pairs of magnetic orbitals of the two trigonally distorted octahedral high-spin M-II ions (M = Ni and Co) as responsible for the overall ferromagnetic coupling observed in 4 and 5 in agreement with a spin polarization mechanism. The decrease of the overall ferromagnetic coupling from 4 to 5 is in turn explained by the additional antiferromagnetic exchange contribution involving the d(xy) pair of magnetic orbitals of the two trigonally distorted octahedral high-spin Co-II ions across the sigma-type pathway of the meta-substituted phenylene spacers.
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