Abstract: The transitional nucleus Xe-131 is investigated after multinucleon transfer in the Xe-136 + Pb-208 and Xe-136 +U-238 reactions employing the high-resolution Advanced gamma-Tracking Array (AGATA) coupled to the magnetic spectrometer PRISMA at the Laboratori Nazionali di Legnaro, Italy, and as an elusive reaction product in the fusion-evaporation reaction Sn-124(B-11) ,p3n)Xe-131 employing the High-efficiency Observatory for gamma-Ray Unique Spectroscopy (HORUS) gamma-ray array coupled to a double-sided silicon strip detector at the University of Cologne, Germany. The level scheme of Xe-131 is extended to 5 MeV. A pronounced backbending is observed at (h) over bar omega approximate to 0.4 MeV along the negative-parity one-quasiparticle vh(11/12)(alpha = -1/2) band. The results are compared to the high-spin systematics of the Z = 54 isotopes and the N = 77 isotones. Large-scale shell-model calculations employing the PQM130, SN100PN, GCN50:82, SN100-KTH, and a realistic effective interaction reproduce the experimental findings and provide guidance to elucidate the structure of the high-spin states. Further calculations in Xe129-132 provide insight into the changing nuclear structure along the Xe chain towards the N = 82 shell closure. Proton occupancy in the pi 0h(11/2) orbital is found to be decisive for the description of the observed backbending phenomenon.