Abstract: We demonstrate that the eight multipole parameters describing the spin state of the Z boson are able to disentangle known Z production mechanisms and signals from new physics at the LHC. They can be extracted from appropriate asymmetries in the angular distribution of lepton pairs from the Z boson decay. The power of this analysis is illustrated by (1) the production of Z boson plus jets; (2) Z boson plus missing transverse energy; (3) W and Z bosons originating from the two-body decay of a heavy resonance.