Abstract: We consider special classes of Palatini f(R) theories, featured by additional Loop Quantum Gravity inspired terms, with the aim of identifying a set of modified Ashtekar canonical variables, which still preserve the SU(2) gauge structure of the standard theory. In particular, we allow for affine connection to be endowed with torsion, which turns out to depend on the additional scalar degree affecting Palatini f( R) gravity, and in this respect we successfully construct a novel Gauss constraint. We analyze the role of the additional scalar field, outlining as it acquires a dynamical character by virtue of a non vanishing Immirzi parameter, and we describe some possible effects on the area operator stemming from such a revised theoretical framework. Finally, we compare our results with earlier studies in literature, discussing differences between metric and Palatini approaches. It is worth noting how the Hamiltonian turns out to be different in the two cases. The results can be reconciled when the analysis is performed in the Einstein frame.