Abstract: A combined amplitude analysis is performed for the decays B0-+ D0D thorn s & pi;- and B thorn -+ D-D thorn s & pi; thorn , which are related by isospin symmetry. The analysis is based on data collected by the LHCb detector in proton -proton collisions at center-of-mass energies of 7, 8, and 13 TeV. The full data sample corresponds to an integrated luminosity of 9 fb-1. Two new resonant states with masses of 2.908 ⠂ 0.011 ⠂ 0.020 GeV and widths of 0.136 ⠂ 0.023 ⠂ 0.013 GeV are observed, which decay to D thorn s & pi; thorn and D thorn s & pi;- respectively. The former state indicates the first observation of a doubly charged open-charm tetraquark state with minimal quark content 1/2cs over bar ud over bar ⠃, and the latter state is a neutral tetraquark composed of 1/2cs over bar u over bar d ⠃ quarks. Both states are found to have spin-parity of 0 thorn , and their resonant parameters are consistent with each other, which suggests that they belong to an isospin triplet.