|
Dul, M. C., Lescouezec, R., Chamoreau, L. M., Journaux, Y., Carrasco, R., Castellano, M., et al. (2012). Self-assembly, metal binding ability, and magnetic properties of dinickel(II) and dicobalt(II) triple mesocates. CrystEngComm, 14(17), 5639–5648.
Abstract: Two metallacyclic complexes of general formula Na-8[(M2L3)-L-II]center dot xH(2)O [M = Ni (4) and Co (5) with x = 15 (4) and 17 (5)] have been self-assembled in aqueous solution from N,N'-1,3-phenylenebis(oxamic acid) (H4L) and M2+ ions in a ligand/metal molar ratio of 3 : 2 in the presence of NaOH acting as base. X-Ray structural analyses of 4 and 5 show triple-stranded, dinuclear anions of the meso-helicate-type (so-called mesocates) with C-3h molecular symmetry. The two octahedral metal-tris(oxamate) moieties of opposite chiralities (Delta, Lambda form) are connected by three m-phenylene spacers at intermetallic distances of 6.822(2) (4) and 6.868(2) angstrom (5) to give a metallacryptand core. In the crystal lattice, the binding of these heterochiral dinickel(II) and dicobalt(II) triple mesocates to sodium(I) ions leads to oxamato-bridged heterobimetallic three-dimensional open-frameworks with a hexagonal diamond architecture having small pores of 17.566(4) (4) and 17.640(2) angstrom (5) in diameter where the crystallization water molecules and the sodium(I) countercations are hosted. Variable temperature (2.0-300 K) magnetic susceptibility measurements reveal relatively anisotropic S = 2 Ni-2(II) (4) and S = 3 Co-2(II) (5) ground states resulting from the moderate to weak intramolecular ferromagnetic coupling between the two high-spin Ni-II (S-Ni = 1) or Co-II (S-Co = 3/2) ions across the m-phenylenediamidate bridges [J = +3.6 (4) and +1.1 cm(-1) (5); H = -JS(1)center dot S-2]. A simple molecular orbital analysis of the electron exchange interaction identifies the p-type pathways of the meta-substituted phenylene spacers involving the d(z2) and d(x2-y2) pairs of magnetic orbitals of the two trigonally distorted octahedral high-spin M-II ions (M = Ni and Co) as responsible for the overall ferromagnetic coupling observed in 4 and 5 in agreement with a spin polarization mechanism. The decrease of the overall ferromagnetic coupling from 4 to 5 is in turn explained by the additional antiferromagnetic exchange contribution involving the d(xy) pair of magnetic orbitals of the two trigonally distorted octahedral high-spin Co-II ions across the sigma-type pathway of the meta-substituted phenylene spacers.
|
|
|
Pierre Auger Collaboration(Abreu, P. et al), & Pastor, S. (2012). Search for Point-like Sources of Ultra-high Energy Neutrinos at the Pierre Auger Observatory and Improved Limit on the Diffuse Flux of Tau Neutrinos. Astrophys. J. Lett., 755(1), L4–7pp.
Abstract: The surface detector array of the Pierre Auger Observatory can detect neutrinos with energy E-nu between 10(17) eV and 10(20) eV from point-like sources across the sky south of +55 degrees and north of -65 degrees declinations. A search has been performed for highly inclined extensive air showers produced by the interaction of neutrinos of all flavors in the atmosphere (downward-going neutrinos), and by the decay of tau leptons originating from tau neutrino interactions in Earth's crust (Earth-skimming neutrinos). No candidate neutrinos have been found in data up to 2010 May 31. This corresponds to an equivalent exposure of similar to 3.5 years of a full surface detector array for the Earth-skimming channel and similar to 2 years for the downward-going channel. An improved upper limit on the diffuse flux of tau neutrinos has been derived. Upper limits on the neutrino flux from point-like sources have been derived as a function of the source declination. Assuming a differential neutrino flux k(PS) . E-nu(-2). from a point-like source, 90% confidence level upper limits for k(PS) at the level of approximate to 5x10(-7) and 2.5x10(-6) GeV cm(-2) s(-1) have been obtained over a broad range of declinations from the searches for Earth-skimming and downward-going neutrinos, respectively.
|
|
|
Aguilar, A. C., Binosi, D., & Papavassiliou, J. (2012). Unquenching the gluon propagator with Schwinger-Dyson equations. Phys. Rev. D, 86(1), 014032–24pp.
Abstract: In this article we use the Schwinger-Dyson equations to compute the nonperturbative modifications caused to the infrared finite gluon propagator (in the Landau gauge) by the inclusion of a small number of quark families. Our basic operating assumption is that the main bulk of the effect stems from the "one-loop dressed'' quark loop contributing to the full gluon self-energy. This quark loop is then calculated, using as basic ingredients the full quark propagator and quark-gluon vertex; for the quark propagator we use the solution obtained from the quark-gap equation, while for the vertex we employ suitable Ansatze, which guarantee the transversality of the answer. The resulting effect is included as a correction to the quenched gluon propagator, obtained in recent lattice simulations. Our main finding is that the unquenched propagator displays a considerable suppression in the intermediate momentum region, which becomes more pronounced as we increase the number of active quark families. The influence of the quarks on the saturation point of the propagator cannot be reliably computed within the present scheme; the general tendency appears to be to decrease it, suggesting a corresponding increase in the effective gluon mass. The renormalization properties of our results, and the uncertainties induced by the unspecified transverse part of the quark-gluon vertex, are discussed. Finally, the gluon propagator is compared with the available unquenched lattice data, showing rather good agreement.
|
|
|
BABAR Collaboration(Lees, J. P. et al), Lopez-March, N., Martinez-Vidal, F., & Oyanguren, A. (2012). Cross sections for the reactions e(+)e(-) -> K+K-pi(+)pi(-), K+K-pi(0)pi(0), and K+K-K+K- measured using initial-state radiation events. Phys. Rev. D, 86(1), 012008–34pp.
Abstract: We study the processes e(+)e(-) -> K+K-pi(+)pi(-)gamma, K+K-pi(0)pi(0)gamma, and K+K-K+K-gamma, where the photon is radiated from the initial state. About 84000, 8000, and 4200 fully reconstructed events, respectively, are selected from 454 fb(-1) of BABAR data. The invariantmass of the hadronic final state defines the e(+)e(-) center-of- mass energy, so that the K+K-pi(+)pi(-)gamma data can be compared with direct measurements of the e(+)e(-) -> K+K-pi(+)pi(-) reaction. No directmeasurements exist for the e(+)e(-) -> K+K-pi(0)pi(0) or e(+)e(-) -> K+K-K+K- reactions, andwe present an update of our previous result based on a data sample that is twice as large. Studying the structure of these events, we find contributions froma number of intermediate states and extract their cross sections. In particular, we perform a more detailed study of the e(+)e(-) -> phi(1020)pi pi gamma reaction and confirm the presence of the Y(2175) resonance in the phi(1020)integral(0)(980) and K+K-integral(0)(980) modes. In the charmonium region, we observe the J/psi in all three final states and in several intermediate states, as well as the psi(2S) in some modes, and measure the corresponding products of branching fraction and electron width.
|
|
|
ATLAS Collaboration(Aad, G. et al), Amoros, G., Cabrera Urban, S., Castillo Gimenez, V., Costa, M. J., Ferrer, A., et al. (2012). Measurement of inclusive jet and dijet production in pp collisions at root s=7 TeV using the ATLAS detector. Phys. Rev. D, 86(1), 014022–63pp.
Abstract: Inclusive jet and dijet cross sections have been measured in proton-proton collisions at a center-of-mass energy of 7 TeV using the ATLAS detector at the Large Hadron Collider. The cross sections were measured using jets clustered with the anti-kt algorithm with parameters R = 0.4 and R = 0.6. These measurements are based on the 2010 data sample, consisting of a total integrated luminosity of 37 pb(-1). Inclusive jet double-differential cross sections are presented as a function of jet transverse momentum, in bins of jet rapidity. Dijet double-differential cross sections are studied as a function of the dijet invariant mass, in bins of half the rapidity separation of the two leading jets. The measurements are performed in the jet rapidity range vertical bar y vertical bar < 4.4, covering jet transverse momenta from 20 GeV to 1.5 TeV and dijet invariant masses from 70 GeV to 5 TeV. The data are compared to expectations based on next-to-leading-order QCD calculations corrected for nonperturbative effects, as well as to next-to-leading-order Monte Carlo predictions. In addition to a test of the theory in a new kinematic regime, the data also provide sensitivity to parton distribution functions in a region where they are currently not well-constrained.
|
|