Abstract: We study the effect of a uniform magnetic field B on the decays pi- > l- nu_l bar, where l(-)=e(-), μ(-), carrying out a general analysis that includes four pi (-) decay constants. Taking the values of these constants from a chiral effective Nambu-Jona-Lasinio (NJL) model, it is seen that the total decay rate gets strongly increased with respect to the B = 0 case, with an enhancement factor ranging from similar to 10 for eB = 0.1 GeV2 up to similar to 10(3) for eB = 1 GeV2. The ratio between electronic and muonic decays gets also enhanced, reaching a value of about 1 : 2 for eB = 1 GeV2. In addition, we find that for large B the angular distribution of outgoing antineutrinos shows a significant suppression in the direction of the magnetic field.