Abstract: The LHC is the perfect environment for the study of new physics in the top quark sector. We study the possibility of detecting signals of heavy color-octet vector resonances, through the charge asymmetry, in t (t) over bar + jet events. Besides contributions with the t (t) over bar pair in a color-singlet state, the asymmetry gets also contributions which are proportional to the color factor f(abc)(2). This process is particularly interesting for extra-dimensional models, where the inclusive charge asymmetry generated by Kaluza-Klein excitations of the gluon vanishes at the tree level. We find that the statistical significance for the measurement of such an asymmetry is sizable for different values of the coupling constants and already at low energies.