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Author |
Dul, M.C.; Lescouezec, R.; Chamoreau, L.M.; Journaux, Y.; Carrasco, R.; Castellano, M.; Ruiz-Garcia, R.; Cano, J.; Lloret, F.; Julve, M.; Ruiz-Perez, C.; Fabelo, O.; Pardo, E. |
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Title |
Self-assembly, metal binding ability, and magnetic properties of dinickel(II) and dicobalt(II) triple mesocates |
Type |
Journal Article |
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Year |
2012 |
Publication |
CrystEngComm |
Abbreviated Journal |
CrystEngComm |
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Volume |
14 |
Issue |
17 |
Pages |
5639-5648 |
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Keywords |
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Abstract |
Two metallacyclic complexes of general formula Na-8[(M2L3)-L-II]center dot xH(2)O [M = Ni (4) and Co (5) with x = 15 (4) and 17 (5)] have been self-assembled in aqueous solution from N,N'-1,3-phenylenebis(oxamic acid) (H4L) and M2+ ions in a ligand/metal molar ratio of 3 : 2 in the presence of NaOH acting as base. X-Ray structural analyses of 4 and 5 show triple-stranded, dinuclear anions of the meso-helicate-type (so-called mesocates) with C-3h molecular symmetry. The two octahedral metal-tris(oxamate) moieties of opposite chiralities (Delta, Lambda form) are connected by three m-phenylene spacers at intermetallic distances of 6.822(2) (4) and 6.868(2) angstrom (5) to give a metallacryptand core. In the crystal lattice, the binding of these heterochiral dinickel(II) and dicobalt(II) triple mesocates to sodium(I) ions leads to oxamato-bridged heterobimetallic three-dimensional open-frameworks with a hexagonal diamond architecture having small pores of 17.566(4) (4) and 17.640(2) angstrom (5) in diameter where the crystallization water molecules and the sodium(I) countercations are hosted. Variable temperature (2.0-300 K) magnetic susceptibility measurements reveal relatively anisotropic S = 2 Ni-2(II) (4) and S = 3 Co-2(II) (5) ground states resulting from the moderate to weak intramolecular ferromagnetic coupling between the two high-spin Ni-II (S-Ni = 1) or Co-II (S-Co = 3/2) ions across the m-phenylenediamidate bridges [J = +3.6 (4) and +1.1 cm(-1) (5); H = -JS(1)center dot S-2]. A simple molecular orbital analysis of the electron exchange interaction identifies the p-type pathways of the meta-substituted phenylene spacers involving the d(z2) and d(x2-y2) pairs of magnetic orbitals of the two trigonally distorted octahedral high-spin M-II ions (M = Ni and Co) as responsible for the overall ferromagnetic coupling observed in 4 and 5 in agreement with a spin polarization mechanism. The decrease of the overall ferromagnetic coupling from 4 to 5 is in turn explained by the additional antiferromagnetic exchange contribution involving the d(xy) pair of magnetic orbitals of the two trigonally distorted octahedral high-spin Co-II ions across the sigma-type pathway of the meta-substituted phenylene spacers. |
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Address |
[Dul, Marie-Claire; Lescouezec, Rodrigue; Chamoreau, Lise-Marie; Journaux, Yves] Univ Paris 06, Inst Parisien Chim Mol, F-75005 Paris, France, Email: rodrigue.lescouezec@upmc.fr; |
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Royal Soc Chemistry |
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English |
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ISSN  |
1466-8033 |
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Notes |
WOS:000306972100041 |
Approved |
no |
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Is ISI |
yes |
International Collaboration |
yes |
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Call Number |
IFIC @ pastor @ |
Serial |
1125 |
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Author |
Bertone, G.; Cerdeño, D.G.; Fornasa, M.; Ruiz de Austri, R.; Strege, C.; Trotta, R. |
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Title |
Global fits of the cMSSM including the first LHC and XENON100 data |
Type |
Journal Article |
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Year |
2012 |
Publication |
Journal of Cosmology and Astroparticle Physics |
Abbreviated Journal |
J. Cosmol. Astropart. Phys. |
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Volume |
01 |
Issue |
1 |
Pages |
015 - 23pp |
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Keywords |
dark matter theory; supersymmetry and cosmology |
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Abstract |
We present updated global fits of the constrained Minimal Supersymmetric Standard Model (cMSSM), including the most recent constraints from the ATLAS and CMS detectors at the LHC, as well as the most recent results of the XENON100 experiment. Our robust analysis takes into account both astrophysical and hadronic uncertainties that enter in the calculation of the rate of WIMP-induced recoils in direct detection experiment. We study the consequences for neutralino Dark Matter, and show that current direct detection data already allow to robustly rule out the so-called Focus Point region, therefore demonstrating the importance of particle astrophysics experiments in constraining extensions of the Standard Model of Particle Physics. We also observe an increased compatibility between results obtained from a Bayesian and a Frequentist statistical perspective. We find that upcoming ton-scale direct detection experiments will probe essentially the entire currently favoured region (at the 99% level), almost independently of the statistical approach used. Prospects for indirect detection of the cMSSM are further reduced. |
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Address |
[Bertone, Gianfranco] Univ Amsterdam, GRAPPA Inst, NL-1090 GL Amsterdam, Netherlands, Email: gf.bertone@gmail.com |
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Publisher |
Iop Publishing Ltd |
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Language |
English |
Summary Language |
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Original Title |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1475-7516 |
ISBN |
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Conference |
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Notes |
WOS:000300403300015 |
Approved |
no |
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Is ISI |
yes |
International Collaboration |
yes |
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Call Number |
IFIC @ pastor @ |
Serial |
936 |
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Author |
Bertone, G.; Cumberbatch, D.; Ruiz de Austri, R.; Trotta, R. |
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Title |
Dark Matter searches: the nightmare scenario |
Type |
Journal Article |
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Year |
2012 |
Publication |
Journal of Cosmology and Astroparticle Physics |
Abbreviated Journal |
J. Cosmol. Astropart. Phys. |
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Volume |
01 |
Issue |
1 |
Pages |
004 - 24pp |
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Keywords |
dark matter theory; dark matter experiments; neutrino detectors; solar and atmospheric neutrinos |
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Abstract |
The unfortunate case where the Large Hadron Collider (LHC) fails to discover physics Beyond the Standard Model (BSM) is sometimes referred to as the “Nightmare scenario” of particle physics. We study the consequences of this hypothetical scenario for Dark Matter (DM), in the framework of the constrained Minimal Supersymmetric Standard Model (cMSSM). We evaluate the surviving regions of the cMSSM parameter space after null searches at the LHC, using several different LHC configurations, and study the consequences for DM searches with ton-scale direct detectors and the IceCube neutrino telescope. We demonstrate that ton-scale direct detection experiments will be able to conclusively probe the cMSSM parameter space that would survive null searches at the LHC with 100 fb(-1) of integrated luminosity at 14TeV. We also demonstrate that IceCube (80 strings plus DeepCore) will be able to probe as much as similar or equal to 17% of the currently favoured parameter space after 5 years of observation. |
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Address |
[Bertone, Gianfranco] Univ Zurich, Inst Theoret Phys, CH-8057 Zurich, Switzerland, Email: bertone@iap.fr |
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Publisher |
Iop Publishing Ltd |
Place of Publication |
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Language |
English |
Summary Language |
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Original Title |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1475-7516 |
ISBN |
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Area |
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Expedition |
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Conference |
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Notes |
WOS:000300403300004 |
Approved |
no |
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Is ISI |
yes |
International Collaboration |
yes |
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Call Number |
IFIC @ pastor @ |
Serial |
937 |
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Author |
Bringmann, T.; Donato, F.; Lineros, R.A. |
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Title |
Radio data and synchrotron emission in consistent cosmic ray models |
Type |
Journal Article |
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Year |
2012 |
Publication |
Journal of Cosmology and Astroparticle Physics |
Abbreviated Journal |
J. Cosmol. Astropart. Phys. |
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Volume |
01 |
Issue |
1 |
Pages |
049 - 12pp |
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Keywords |
cosmic ray theory; dark matter theory |
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Abstract |
It is well established that phenomenological two-zone diffusion models of the galactic halo can very well reproduce cosmic-ray nuclear data and the observed antiproton flux. Here, we consider lepton propagation in such models and compute the expected galactic population of electrons, as well as the diffuse synchrotron emission that results from their interaction with galactic magnetic fields. We find models in agreement not only with cosmic ray data but also with radio surveys at essentially all frequencies. Requiring such a globally consistent description strongly disfavors very large (L greater than or similar to 15 kpc) and, even stronger, small (L less than or similar to 1 kpc) effective diffusive halo sizes. This has profound implications for, e.g., in direct dark matter searches. |
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Address |
[Bringmann, Torsten] Univ Hamburg, Inst Theoret Phys, D-22761 Hamburg, Germany, Email: torsten.bringmann@desy.de |
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Publisher |
Iop Publishing Ltd |
Place of Publication |
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Language |
English |
Summary Language |
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Original Title |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1475-7516 |
ISBN |
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Area |
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Conference |
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Notes |
WOS:000300403300049 |
Approved |
no |
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Is ISI |
yes |
International Collaboration |
yes |
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Call Number |
IFIC @ pastor @ |
Serial |
938 |
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Author |
Fornengo, N.; Lineros, R.A.; Regis, M.; Taoso, M. |
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Title |
Galactic synchrotron emission from WIMPs at radio frequencies |
Type |
Journal Article |
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Year |
2012 |
Publication |
Journal of Cosmology and Astroparticle Physics |
Abbreviated Journal |
J. Cosmol. Astropart. Phys. |
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Volume |
01 |
Issue |
1 |
Pages |
005 - 25pp |
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Keywords |
dark matter theory; cosmic ray theory; absorption and radiation processes |
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Abstract |
Dark matter annihilations in the Galactic halo inject relativistic electrons and positrons which in turn generate a synchrotron radiation when interacting with the galactic magnetic field. We calculate the synchrotron flux for various dark matter annihilation channels, masses, and astrophysical assumptions in the low-frequency range and compare our results with radio surveys from 22 MHz to 1420 MHz. We find that current observations are able to constrain particle dark matter with “thermal” annihilation cross-sections, i.e. (sigma v) = 3 x 10(-26) cm(3) s(-1); and masses M-DM less than or similar to 10 GeV. We discuss the dependence of these bounds on the astrophysical assumptions, namely galactic dark matter distribution, cosmic rays propagation parameters, and structure of the galactic magnetic field. Prospects for detection in future radio surveys are outlined. |
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Address |
[Fornengo, Nicolao; Regis, Marco] Univ Turin, Dipartimento Fis Teor, Ist Nazl Fis Nucl, I-10125 Turin, Italy, Email: fornengo@to.infn.it |
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Publisher |
Iop Publishing Ltd |
Place of Publication |
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Editor |
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Language |
English |
Summary Language |
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Original Title |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1475-7516 |
ISBN |
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Area |
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Expedition |
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Conference |
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Notes |
WOS:000300403300005 |
Approved |
no |
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Is ISI |
yes |
International Collaboration |
yes |
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Call Number |
IFIC @ pastor @ |
Serial |
939 |
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