Abstract: We use a O(alpha(s). Lambda(QCD)/m(c)) heavy quark effective theory scheme, where only O(Lambda(QCD)/mb) corrections are neglected, to study the matrix elements of the scalar, pseudoscalar, vector, axial-vector and tensor currents between the Lambda(b) ground state and the odd parity charm Lambda(c)(2595)(+) and Lambda(c)(2625)(+) resonances. We show that in the near-zero recoil regime, the scheme describes reasonably well, taking into account uncertainties, the results for the 24 form factors obtained in lattice QCD (LQCD) just in terms of only four Isgur-Wise (IW) functions. We also find some support for the possibility that the Lambda(c)(2595)(+) and Lambda(c)(2625)(+) resonances might form a heavy quark spin symmetry (HQSS) doublet. However, we argue that the available LQCD description of these two resonances is not accurate enough to disentangle the possible effects of the Sigma(c)pi and Sigma(c)*pi thresholds, located only a few MeV above their position, and that it cannot be ruled out that these states are not HQSS partners. Finally, we study the ratio d Gamma/[Lambda(b) -> Lambda(c,1/2)-*l (v) over bar (l)]/dq(2)/d Gamma/[Lambda(b) -> Lambda(c,3/2)-*l (v) over bar (l)]/dq(2) of the Standard Model differential semileptonic decay widths, with q the four-momentum transferred between the initial and final hadrons. We provide a natural explanation for the existence of large deviations, near the zero recoil, of this ratio from 1=2 (value predicted in the infinite heavy quark mass limit, assuming that the Lambda(c,1/2)- and Lambda(c,3/2)- are the two members of a HQSS doublet) based on S-wave contributions to the Lambda(b) -> Lambda(c,1/2)- decay amplitude driven by a subleading IW function.