Abstract: We study the influence of lepton flavor asymmetries on the formation and the mass spectrum of primordial black holes. We estimate the detectability of their mergers with LIGO/Virgo and show that the currently published gravitational wave events may actually be described by a primordial black hole spectrum from nonzero asymmetries. We suggest to use gravitational-wave astronomy as a novel tool to probe how lepton flavor asymmetric the Universe has been before the onset of neutrino oscillations.