Abstract: We derive a sum rule which shows that the Froissart-Martin bound for the asymptotic behaviour of the pi pi total cross sections at high energies, if modulated by the Lukaszuk-Martin coefficient of the leading log(2)s behaviour, cannot be an optimal bound in QCD. We next compute the total cross sections for pi(+)pi(-), pi(+/-)pi(0) and pi(0)pi(0) scattering within the framework of the constituent chiral quark model (C chi QM) in the limit of a large number of colours N-c and discuss their asymptotic behaviours. The same pi pi cross sections are also discussed within the general framework of Large-N-c QCD and we show that it is possible to make an Ansatz for the isospin I = 1 and I = 0 spectrum which satisfy the Froissart-Martin bound with coefficients which, contrary to the Lukaszuk-Martin coefficient, are not singular in the chiral limit and have the correct Large-N-c counting. We finally propose a simple phenomenological model which matches the low energy behaviours of the sigma(total)(pi +/-pi 0)(s) cross section predicted by the CxQM with the high energy behaviour predicted by the Large-N-c Ansatz. The magnitude of these cross sections at very high energies is of the order of those observed for the pp and pp scattering total cross sections.