Abstract: We apply the general formalism derived by Penalva et al. [Phys. Rev. D 101, 113004 (2020)] to the semileptonic decay of pseudoscalar mesons containing a b quark. While present (B) over bar -> D-(*()) data give the strongest evidence in favor of lepton flavor universality violation, the observables that are normally considered are not able to distinguish between different new physics (NP) scenarios. In the above reference we discussed the relevant role that the various contributions to the double differential decay widths d(2)Gamma (d omega d cos theta(l)) and d(2)Gamma (d omega dE(l)) could play to this end. Here omega is the product of the two hadron fourvelocities, theta(l) is the angle made by the final lepton and final hadron three-momenta in the center of mass of the final two-lepton system, and E-l is the final charged lepton energy in the laboratory system. The formalism was applied by Penalva et al. to the analysis of the Lambda(b) -> Lambda(c) semileptonic decay, showing the new observables were able to tell apart different NP scenarios. Here we analyze the (B) over barc -> eta(c)tau(nu) over bar (tau), (B) over barc -> J/psi tau(nu) over bar (tau), (B) over bar -> D tau(nu) over bar (tau) and (B) over bar -> D*tau(nu) over bar (tau) , semileptonic decays. We find that, as a general rule, the (B) over barc -> J/psi observables, even including (tau) polarization, are less optimal for distinguishing between NP scenarios than those obtained from (B) over barc -> eta(c) decays, or those presented by Penalva et al. for the related Lambda(b) -> Lambda(c) semileptonic decay. Finally, we show that (B) over bar -> D and (B) over barc -> eta(c) , and (B) over bar -> D* and (B) over barc -> J/psi decay observables exhibit similar behaviors.