Abstract: Achieving a precise description of the internal structure of hadrons is crucial for deciphering the hidden properties and symmetries of fundamental particles. It is a hard task since there are several bottlenecks in obtaining theoretical predictions starting from first principles. In order to complement highly accurate experiments, it is necessary to use ingenious strategies to impose constraints from the theory side. In this article, we describe how photons can be used to unveil the internal structure of hadrons. We explore how to describe NLO QCD plus LO QED corrections to hadron plus photon production at colliders and discuss the impact of these effects on the experimental measurements.