Abstract: Better understanding the mechanisms of nanoparticle permeation through membranes and packaging polymers has important implications for the evaluation of drug transdermal uptake, in food safety and the environmental implications of nanotechnology. In this study, permeation of 21 nm diameter silver nanoparticles (AgNPs) was tested using Side-Bi-Side and Franz static diffusion cells through hydrophilic 0.1 and 0.05 lm pore diameter 125 μm thick synthetic cellulose membranes, and 16 and 120 μm thick low-density polyethylene (LDPE) films. Experiments performed with LDPE films discarded permeation of AgNPs or Ag ions over the investigated time-frame in both diffusion systems. But controlled release of AgNPs has been quantified using semipermeable hydrophilic membranes. The permeation followed a quasi-linear time-dependent model during the experimental time-frame, which represents surface reaction-limited permeation. Diffusive flux, diffusion coefficients, and membrane permeability were determined as a function of pore size and diffusion model. Concentration gradient and pore size were key to understand mass transfer phenomena in the diffusion systems.

Abstract: We use the latest constraints on the population of stellar origin binary black holes (SOBBH) from LIGO/Virgo/KAGRA (LVK) observations, to estimate the stochastic gravi-tational wave background (SGWB) they generate in the frequency band of LISA. In order to account for the faint and distant binaries, which contribute the most to the SGWB, we extend the merger rate at high redshift assuming that it tracks the star formation rate. We adopt different methods to compute the SGWB signal: we perform an analytical evaluation, we use Monte Carlo sums over the SOBBH population realisations, and we account for the role of the detector by simulating LISA data and iteratively removing the resolvable signals until only the confusion noise is left. The last method allows the extraction of both the expected SGWB and the number of resolvable SOBBHs. Since the latter are few for signal-to-noise ratio thresholds larger than five, we confirm that the spectral shape of the SGWB in the LISA band agrees with the analytical prediction of a single power law. We infer the probability dis-tribution of the SGWB amplitude from the LVK GWTC-3 posterior of the binary population model: at the reference frequency of 0.003 Hz it has an interquartile range of h(2 Omega)GW(f = 3 x 10(-3) Hz) is an element of [5.65, 11.5] x 10(-13), in agreement with most previous estimates. We then perform a MC analysis to assess LISA's capability to detect and characterise this signal. Ac-counting for both the instrumental noise and the galactic binaries foreground, with four years of data, LISA will be able to detect the SOBBH SGWB with percent accuracy, narrowing down the uncertainty on the amplitude by one order of magnitude with respect to the range of possible amplitudes inferred from the population model. A measurement of this signal by LISA will help to break the degeneracy among some of the population parameters, and pro-vide interesting constraints, in particular on the redshift evolution of the SOBBH merger rate.

Abstract: Excited states in the mirror nuclei P-31 and S-31 were populated in the 1p and 1n exit channels of the reaction Ne-20 + C-12, at a beam energy of 33 MeV. The Ne-20 beam was delivered for the first time by the Piave-Alpi accelerator of the Laboratori Nazionali di Legnaro. Angular correlations of coincident gamma-rays and Doppler-shift attenuation lifetime measurements were performed using the multi-detector array GASP in conjunction with the EUCLIDES charged particle detector. In the observed B(E1) strengths, the isoscalar component, amounting to 24% of the isovector one, provides strong evidence for breaking of the isospin symmetry in the A = 31 mass region. Self-consistent beyond mean field calculations using Equation of Motion method based on a chiral potential and including two- and three-body forces reproduce well the experimental B(E1) strengths, reinforcing our conclusion. Coherent mixing from higher-lying states involving the Giant Isovector Monopole Resonance accounts well for the effect observed. The breaking of the isospin symmetry originates from the violation of the charge symmetry of the two- and three-body parts of the potential, only related to the Coulomb interaction.

Abstract: The properties of strange (K, (K) over bar and (K) over bar*) and open-charm (D, (D) over bar and D*) mesons in dense matter are studied using a unitary approach in coupled channels for meson-baryon scattering. In the strangeness sector, the interaction with nucleons always comes through vector-meson exchange, which is evaluated by chiral and hidden gauge Lagrangians. For the interaction of charmed mesons with nucleons we extend the SU(3) Weinberg-Tomozawa Lagrangian to incorporate spin-flavor symmetry and implement a suitable flavor symmetry breaking. The in-medium solution for the scattering amplitude accounts for Pauli blocking effects and meson self-energies. On one hand, we obtain the K, (K) over bar and (K) over bar* spectral functions in the nuclear medium and study their behaviour at finite density, temperature and momentum. We also make an estimate of the transparency ratio of the gamma A -> K+ K*(-) A' reaction, which we propose as a tool to detect in-medium modifications of the (K) over bar* meson. On the other hand, in the charm sector, several resonances with negative parity are generated dynamically by the s-wave interaction between pseudoscalar and vector meson multiplets with 1/2(+) and 3/2(+) baryons. The properties of these states in matter are analyzed and their influence on the open-charm meson spectral functions is studied. We finally discuss the possible formation of D-mesic nuclei at FAIR energies.

Abstract: The CERN Neutron Time-Of-Flight (n_TOF) facility is well suited to measure small neutron-induced fission cross sections, as those of subactinides. The cross section ratios of (nat)Pb and (209)Bi relative to (235)U and (238)U were measured using PPAC detectors. The fragment coincidence method allows to unambiguously identify the fission events. The present experiment provides the first results for neutron-induced fission up to 1 GeV for (nat)Pb and (209)Bi. A good agreement with previous experimental data below 200 MeV is shown. The comparison with proton-induced fission indicates that the limiting regime where neutron-induced and proton-induced fission reach equal cross section is close to 1 GeV.