Abstract: Neutron-rich chlorine isotopes were populated in the Ar-40 + Pb-208 multiple transfer reaction via the -1p channels in a fragment-gamma coincident measurement employing the Prisma-Clara setup. New gamma transitions have been identified and, together with already available data, level schemes have been revised and compared with the results of large-scale sd-pf shell-model calculations. The evolution of the energy splitting between the s(1/2) and d(3/2) orbitals and the increased mixing of different proton configurations in the populated Cl isotopic chain have been deduced by inspecting the shell-model wave functions.