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Author |
Dul, M.C.; Lescouezec, R.; Chamoreau, L.M.; Journaux, Y.; Carrasco, R.; Castellano, M.; Ruiz-Garcia, R.; Cano, J.; Lloret, F.; Julve, M.; Ruiz-Perez, C.; Fabelo, O.; Pardo, E. |
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Title |
Self-assembly, metal binding ability, and magnetic properties of dinickel(II) and dicobalt(II) triple mesocates |
Type |
Journal Article |
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Year |
2012 |
Publication |
CrystEngComm |
Abbreviated Journal |
CrystEngComm |
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Volume |
14 |
Issue |
17 |
Pages |
5639-5648 |
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Keywords |
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Abstract |
Two metallacyclic complexes of general formula Na-8[(M2L3)-L-II]center dot xH(2)O [M = Ni (4) and Co (5) with x = 15 (4) and 17 (5)] have been self-assembled in aqueous solution from N,N'-1,3-phenylenebis(oxamic acid) (H4L) and M2+ ions in a ligand/metal molar ratio of 3 : 2 in the presence of NaOH acting as base. X-Ray structural analyses of 4 and 5 show triple-stranded, dinuclear anions of the meso-helicate-type (so-called mesocates) with C-3h molecular symmetry. The two octahedral metal-tris(oxamate) moieties of opposite chiralities (Delta, Lambda form) are connected by three m-phenylene spacers at intermetallic distances of 6.822(2) (4) and 6.868(2) angstrom (5) to give a metallacryptand core. In the crystal lattice, the binding of these heterochiral dinickel(II) and dicobalt(II) triple mesocates to sodium(I) ions leads to oxamato-bridged heterobimetallic three-dimensional open-frameworks with a hexagonal diamond architecture having small pores of 17.566(4) (4) and 17.640(2) angstrom (5) in diameter where the crystallization water molecules and the sodium(I) countercations are hosted. Variable temperature (2.0-300 K) magnetic susceptibility measurements reveal relatively anisotropic S = 2 Ni-2(II) (4) and S = 3 Co-2(II) (5) ground states resulting from the moderate to weak intramolecular ferromagnetic coupling between the two high-spin Ni-II (S-Ni = 1) or Co-II (S-Co = 3/2) ions across the m-phenylenediamidate bridges [J = +3.6 (4) and +1.1 cm(-1) (5); H = -JS(1)center dot S-2]. A simple molecular orbital analysis of the electron exchange interaction identifies the p-type pathways of the meta-substituted phenylene spacers involving the d(z2) and d(x2-y2) pairs of magnetic orbitals of the two trigonally distorted octahedral high-spin M-II ions (M = Ni and Co) as responsible for the overall ferromagnetic coupling observed in 4 and 5 in agreement with a spin polarization mechanism. The decrease of the overall ferromagnetic coupling from 4 to 5 is in turn explained by the additional antiferromagnetic exchange contribution involving the d(xy) pair of magnetic orbitals of the two trigonally distorted octahedral high-spin Co-II ions across the sigma-type pathway of the meta-substituted phenylene spacers. |
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Address  |
[Dul, Marie-Claire; Lescouezec, Rodrigue; Chamoreau, Lise-Marie; Journaux, Yves] Univ Paris 06, Inst Parisien Chim Mol, F-75005 Paris, France, Email: rodrigue.lescouezec@upmc.fr; |
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Royal Soc Chemistry |
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English |
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Edition |
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ISSN |
1466-8033 |
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Expedition |
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Conference |
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Notes |
WOS:000306972100041 |
Approved |
no |
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Is ISI |
yes |
International Collaboration |
yes |
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Call Number |
IFIC @ pastor @ |
Serial |
1125 |
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Author |
Dorame, L.; Morisi, S.; Peinado, E.; Valle, J.W.F.; Rojas, A.D. |
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Title |
New neutrino mass sum rule from the inverse seesaw mechanism |
Type |
Journal Article |
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Year |
2012 |
Publication |
Physical Review D |
Abbreviated Journal |
Phys. Rev. D |
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Volume |
86 |
Issue |
5 |
Pages |
056001 - 9pp |
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Keywords |
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Abstract |
A class of discrete flavor-symmetry-based models predicts constrained neutrino mass matrix schemes that lead to specific neutrino mass sum rules. One of these implies a lower bound on the effective neutrinoless double beta mass parameter, even for normal hierarchy neutrinos. Here we propose a new model based on the S-4 flavor symmetry that leads to the new neutrino mass sum rule and discuss how to generate a nonzero value for the reactor angle theta(13) indicated by recent experiments, and the resulting correlation with the solar angle theta(12). |
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Address |
[Dorame, L.; Morisi, S.; Peinado, E.; Valle, J. W. F.] Univ Valencia, CSIC, Inst Fis Corpuscular, AHEP Grp, E-46071 Valencia, Spain, Email: dorame@ific.uv.es; |
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Amer Physical Soc |
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English |
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Series Issue |
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Edition |
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ISSN |
1550-7998 |
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Area |
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Conference |
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Notes |
WOS:000308291700005 |
Approved |
no |
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Is ISI |
yes |
International Collaboration |
yes |
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Call Number |
IFIC @ pastor @ |
Serial |
1149 |
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Author |
Dorame, L.; Meloni, D.; Morisi, S.; Peinado, E.; Valle, J.W.F. |
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Title |
Constraining neutrinoless double beta decay |
Type |
Journal Article |
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Year |
2012 |
Publication |
Nuclear Physics B |
Abbreviated Journal |
Nucl. Phys. B |
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Volume |
861 |
Issue |
3 |
Pages |
259-270 |
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Keywords |
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Abstract |
A class of discrete flavor-symmetry-based models predicts constrained neutrino mass matrix schemes that lead to specific neutrino mass sum-rules (MSR). We show how these theories may constrain the absolute scale of neutrino mass, leading in most of the cases to a lower bound on the neutrinoless double beta decay effective amplitude. |
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Address |
[Dorame, L.; Morisi, S.; Peinado, E.; Valle, J. W. F.] Univ Valencia, AHEP Grp, Inst Fis Corpuscular, CSIC,Edificio Inst Paterna, E-46071 Valencia, Spain, Email: dorame@ific.uv.es; |
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Publisher |
Elsevier Science Bv |
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English |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0550-3213 |
ISBN |
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Conference |
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Notes |
WOS:000304239200001 |
Approved |
no |
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Is ISI |
yes |
International Collaboration |
yes |
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Call Number |
IFIC @ pastor @ |
Serial |
1030 |
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Author |
Donini, A.; Hernandez, P.; Lopez-Pavon, J.; Maltoni, M.; Schwetz, T. |
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Title |
The minimal 3+2 neutrino model versus oscillation anomalies |
Type |
Journal Article |
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Year |
2012 |
Publication |
Journal of High Energy Physics |
Abbreviated Journal |
J. High Energy Phys. |
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Volume |
07 |
Issue |
7 |
Pages |
161 - 20pp |
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Keywords |
Neutrino Physics; Beyond Standard Model |
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Abstract |
We study the constraints imposed by neutrino oscillation experiments on the minimal extension of the Standard Model that can explain neutrino masses, which requires the addition of just two singlet Weyl fermions. The most general renormalizable couplings of this model imply generically four massive neutrino mass eigenstates while one remains massless: it is therefore a minimal 3+2 model. The possibility to account for the confirmed solar, atmospheric and long-baseline oscillations, together with the LSND/MiniBooNE and reactor anomalies is addressed. We find that the minimal model can fit oscillation data including the anomalies better than the standard 3 nu model and similarly to the 3 + 2 phenomenological models, even though the number of free parameters is much smaller than in the latter. Accounting for the anomalies in the minimal model favours a normal hierarchy of the light states and requires a large reactor angle, in agreement with recent measurements. Our analysis of the model employs a new parametrization of seesaw models that extends the Casas-Ibarra one to regimes where higher order corrections in the light-heavy mixings are significant. |
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Address |
[Donini, A.; Hernandez, P.] Univ Valencia, Inst Fis Corpuscular, CSIC, E-46071 Valencia, Spain, Email: andrea.donini@uam.es; |
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Publisher |
Springer |
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Editor |
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English |
Summary Language |
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Original Title |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1126-6708 |
ISBN |
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Medium |
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Area |
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Expedition |
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Conference |
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Notes |
WOS:000307299800039 |
Approved |
no |
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Is ISI |
yes |
International Collaboration |
yes |
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Call Number |
IFIC @ pastor @ |
Serial |
1161 |
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Author |
AGATA Collaboration; Domingo-Pardo, C.; Bazzacco, D.; Doornenbal, P.; Farnea, E.; Gadea, A.; Gerl, J.; Wollersheim, H.J. |
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Title |
Conceptual design and performance study for the first implementation of AGATA at the in-flight RIB facility of GSI |
Type |
Journal Article |
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Year |
2012 |
Publication |
Nuclear Instruments & Methods in Physics Research A |
Abbreviated Journal |
Nucl. Instrum. Methods Phys. Res. A |
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Volume |
694 |
Issue |
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Pages |
297-312 |
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Keywords |
gamma-Ray spectroscopy; Tracking; Monte Carlo |
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Abstract |
The main objective of the Advanced GAmma Tracking Array (AGATA) is the investigation of the structure of exotic nuclei at the new generation of RIB facilities. As part of the preparatory phase for FAIR-NUSTAR, AGATA is going to be installed at the FRS fragmentation facility of the GSI centre for an experimental campaign to be performed in 2012 and 2013. Owing to its gamma-ray tracking capabilities and the envisaged enhancement in resolving power, a series of in-flight gamma-ray spectroscopy experiments are being planned. The present work describes the conceptual design of this first implementation of AGATA at GSI-FRS, and provides information about the expected performance figures. According to the characteristics of each particular experiment, it is foreseen that the target-array distance is adjusted in order to achieve the optimum compromise between detection efficiency and energy resolution, or to cover an specific angular range of the emitted electromagnetic radiation. Thus, a comprehensive Monte Carlo study of the detection sensitivity in terms of photopeak efficiency, resolution and peak-to-total ratio, as a function of the target-array distance is presented. Several configurations have been investigated, and MC-calculations indicate that a remarkable enhancement in resolving power can be achieved when double-cluster AGATA detectors are developed and implemented. Several experimental effects are also investigated. This concerns the impact of passive materials between the target and the array, the angular distribution of the detection efficiency and the influence of target thickness effects and transition lifetimes in the attainable detection sensitivity. A short overview on half-life measurements via lineshape effects utilizing AGATA is also presented. (C) 2012 Elsevier B.V. All rights reserved. |
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Address |
[Domingo-Pardo, C.; Gadea, A.] Univ Valencia, CSIC, IFIC, Valencia, Spain, Email: domingo@ific.uv.es |
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Corporate Author |
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Thesis |
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Publisher |
Elsevier Science Bv |
Place of Publication |
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Editor |
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Language |
English |
Summary Language |
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Original Title |
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Series Editor |
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Series Title |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
0168-9002 |
ISBN |
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Medium |
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Area |
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Expedition |
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Conference |
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Notes |
WOS:000311020500041 |
Approved |
no |
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Is ISI |
yes |
International Collaboration |
yes |
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Call Number |
IFIC @ pastor @ |
Serial |
1240 |
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