PT Journal AU Casas, F Oteo, JA Ros, J TI Unitary transformations depending on a small parameter SO Proceedings of the Royal Society A JI Proc. R. Soc. A PY 2012 BP 685 EP 700 VL 468 IS 2139 DI 10.1098/rspa.2011.0388 LA English DE perturbation theory; quantum mechanics; unitary transformation; Magnus expansion AB We formulate a unitary perturbation theory for quantum mechanics inspired by the Lie-Deprit formulation of canonical transformations. The original Hamiltonian is converted into a solvable one by a transformation obtained through a Magnus expansion. This ensures unitarity at every order in a small parameter. A comparison with the standard perturbation theory is provided. We work out the scheme up to order ten with some simple examples. ER